Determination of Some Sulphonyl Chlorides
Keywords:
Sulphonyl Chlorides, Sulphinic Acids, Oxidimetric Titration, Polarographic Analysis, Benzyl Mercaptan ReductionAbstract
Sulphonyl chlorides, RSO2Cl are compounds of extensive economical, diagnostic and synthetic importance. Subsequently, their determination is of enormous opportunity and countless value. These find significant uses in leather manufacture- tanning, as fat liquoring mediators and for leather impregnation1. Sulphonyl chlorides support as appreciated substances in certification and determination of primary and secondary amines and phenols2. They serve as significant and inexpensive intermediates for the synthesis of economically significant compounds such as sulphonamides, sulphonic acids, sulphonyl hydrazides, sulphones, sulphinic acids and mercaptans. Sulphonamides find wide use in chemotherapy as sulpha drugs and currently used for the synthesis of juvenile hormone analogues3-5 which are further used as potential insecticides and pesticides. Utmost frequently working methods for the determination of these compounds hang on the comparatively facile splitting of their S-Cl bond in hydrolysis kind reactions with water, bases, amines and hydroxylamine, where the chloride is ejected and sulphur leftovers hexavalent in sulphonic acid or their plagiaristic formed in these reactions. Diverse approaches have been conversed and used for the determination of sulphonyl chlorides.
References
1. Olivannau, M.S. and Nayaudamma, Y; J. Sci. Ind. Res., 1969, 28, 293.
2. Skrypnik, Y.G. and Bezrodngi, V. P., Acad. Sci., Ukrainen, USSR, 1982, 901N31/08; Anal., Abstr., 1982, 97, 9.
3. R.K.Mahajan, Ved Parkash Patial and Pamita Sharma, Ind. J. Chem. 1998, 15, 1 & 2, 51-54.
4. R. K. Mahajan and Ved Parkash Patial, Nat. Acad. Sci. India, 72A, 2002, 287.
5. V. P. Patial and Rajnish Dewan, Shodh Shree, 2012, 3, 49-55.
6. Suter, C., “The organic Chemistry of Sulphur”, Wiley and Sons, New York, 1943.
7. Karchmer J. H., “Analytical chemistry of sulphur and its compounds”, Part II. Wiley Intersciences, Newyork, 1972.
8. Ashworth M. R. F., “The determination of sulphur containing groups”, Vol. I and II, Academic Press, Newyork, 1972.
9. Reid E. E., “Organic chemistry of Bivalent Sulphur”, Vol. III, Chemical Publishing Comp., NewYork, 1960.
10. Seaman, W., Norton A. R., Woods, J. T. and Massad, E. A. Ind. Eng. Chem., Anal Ect. 1944, 16, 517.
11. Frehden, O. and Petroianu, S., Rev. Chem. Bucharest, 1965, 16, 223.
12. Frehden, O. and Petroianu, S., Z. Anal Chem.., 1968, 220, 379.
13. Ashworth, M. R. F. and Winter, M., Anal, Chem. Acta, 1963, 29, 75.
14. Ashworth, M. R. F., Walisch, W. and Kronz-Dienhart, G., Anal., Chim. Acta, 1959, 20, 96.
15. Walisch, W, Hertel, D. F. and Ashworth, M. R. F., Chim, Anal. Paris, 1961, 43, 234.
16. Siewinski, M., Kuropatwa, M., Szewezauk., A., Anal. Chem. 1984, 56 (14), 2882-4 (Eng.).
17. Kuznetsov, V. V. and Lyaufer, M. S., Zh. Anal. Khim., 1980, 35 (4) 747-52 (Russ.) (Chem. Abstr. 1980, 93, 142344 J).
18. Mairanovskii, S. G. and Neiman, M. B. Dokl. Akad. Nauk- USSR, 1951, 79, 85.
19. Horner, L. and Nickel, H., Chem. Ber, 1956, 89, 1681.
20. Cernak J. and Blazej A., Chem., Zvesti, 1962, 16, 276.
21. Kovbuz, M. A., Kachanko, I. E., Popova, L. Z. and Vizgert, R. V., Zh. Obshch. Khim., 1968, 38, 1455.
22. Urabe, N. and Yasukochi, K., Denki Kagaku, 1956, 24, 360 ( Chem. Abstr. 51, 14447).
23. Kang, S. W. Oh, H. B., Lec., S. S., Taehaff Hwahakhochi, 1986, 30 (2) 244-50 (Korean ).
24. Nakada, M., Uzawa, A., Fukush, S., Tomita, H., Hirota, M. Nippon Kagakn, 1984, 728-31 (Japan ).
25. Tazerouti, A. Rahal, S; Soumillion J. P. (Inst. Chim; USTHB, Algiers, Algeria) J. Chromatogr. 1992, 596 (1), 132-7 (Eng.).
26. Deskin, W. A., J., Amer. Chem. SOC. 1958, 80, 5680-82.
27. Grindley, D. N., “ An advanced course in Practical Inorganic chemistry “, Butterworths, London, 1964, p. 79.
